Morocco: Marrakech - Doubles - Main |
| 1/8-finals | Kania-Chodun P./Olaru R. | Pennetta F./Schiavone F. | 2:1 (4:6, 6:4, 10:8) | details | 23.04.2013 |
World: Fed Cup - World Group - Doubles - Main |
| | Pennetta F./Schiavone F. | Sestini Hlavackova A./Hradecka L. | CAN. | details | 22.04.2013 |
World: Olympic Games - Doubles - Main |
| 1/8-finals | Chuang C.-J./Hsieh S-W. | Pennetta F./Schiavone F. | 2:1 (63:7, 7:5, 6:4) | details | 01.08.2012 |
| 1/16-finals | Medina Garrigues A./Parra-Santonja A. | Pennetta F./Schiavone F. | 0:2 (64:7, 4:6) | details | 31.07.2012 |
United Kingdom: Wimbledon - Doubles - Main |
| Semi-finals | Pennetta F./Schiavone F. | Sestini Hlavackova A./Hradecka L. | 1:2 (6:2, 3:6, 4:6) | details | 06.07.2012 |
| Quarter-finals | Llagostera Vives N./Martinez Sanchez M. J. | Pennetta F./Schiavone F. | 1:2 (2:6, 7:60, 4:6) | details | 05.07.2012 |
| 1/8-finals | Hsieh S-W./Lisicki S. | Pennetta F./Schiavone F. | WO. | details | 04.07.2012 |
| 1/16-finals | Pennetta F./Schiavone F. | Peschke K./Srebotnik K. | 2:1 (6:3, 4:6, 6:1) | details | 29.06.2012 |
| 1/32-finals | Pavlyuchenkova A./Safarova L. | Pennetta F./Schiavone F. | 1:2 (2:6, 7:5, 4:6) | details | 27.06.2012 |
Netherlands: Hertogenbosch - Doubles - Main |
| Semi-finals | Pennetta F./Schiavone F. | Kirilenko M./Petrova N. | WO. | details | 22.06.2012 |
| Quarter-finals | Pennetta F./Schiavone F. | Begu I./Niculescu M. | 2:1 (6:4, 5:7, 10:3) | details | 20.06.2012 |
| 1/8-finals | Pennetta F./Schiavone F. | Bertens K./Rus A. | 2:0 (7:62, 7:5) | details | 19.06.2012 |
France: French Open - Doubles - Main |
| 1/8-finals | Llagostera Vives N./Martinez Sanchez M. J. | Pennetta F./Schiavone F. | 2:1 (6:3, 2:6, 6:2) | details | 02.06.2012 |
| 1/16-finals | Pennetta F./Schiavone F. | Kerber A./Radwanska A. | 2:1 (3:6, 6:4, 6:2) | details | 31.05.2012 |
| 1/32-finals | Pennetta F./Schiavone F. | Cirstea S./Morita A. | 1:0 RET. (6:2, 2:0) | details | 29.05.2012 |
Italy: Rome - Doubles - Main |
| Quarter-finals | Hampton J./Tatishvili A. | Pennetta F./Schiavone F. | WO. | details | 18.05.2012 |
| 1/8-finals | Pennetta F./Schiavone F. | Peschke K./Srebotnik K. | 2:0 (6:2, 6:4) | details | 17.05.2012 |
| 1/16-finals | Groenefeld A./Martic P. | Pennetta F./Schiavone F. | 0:2 (3:6, 4:6) | details | 16.05.2012 |
Spain: Barcelona - Doubles - Main |
| Final | Errani S./Vinci R. | Pennetta F./Schiavone F. | 2:0 (6:0, 6:2) | details | 15.04.2012 |
| Semi-finals | Pennetta F./Schiavone F. | Begu I./Dominguez Lino L. | 2:0 (7:5, 6:2) | details | 13.04.2012 |
| Quarter-finals | Pennetta F./Schiavone F. | Peer S./Suarez P. | 2:1 (6:1, 3:6, 10:8) | details | 12.04.2012 |
| 1/8-finals | Cirstea S./Koukalova K. | Pennetta F./Schiavone F. | 1:2 (5:7, 6:4, 6:10) | details | 09.04.2012 |
United Arab Emirates: Dubai - Doubles - Main |
| 1/8-finals | Atawo R./Spears A. | Pennetta F./Schiavone F. | 2:1 (3:6, 7:62, 10:6) | details | 22.02.2012 |
Qatar: Doha - Doubles - Main |
| 1/16-finals | Dushevina V./Peer S. | Pennetta F./Schiavone F. | 2:1 (6:2, 5:7, 10:7) | details | 13.02.2012 |
United Arab Emirates: Dubai - Doubles - Main |
| 1/8-finals | Pennetta F./Schiavone F. | Mattek-Sands B./Shaughnessy M. | WO. | details | 17.02.2011 |
| 1/16-finals | Pennetta F./Schiavone F. | Errani S./Vinci R. | 2:1 (6:4, 4:6, 10:6) | details | 15.02.2011 |
New Zealand: Auckland - Doubles - Main |
| Semi-finals | Black C./Huber L. | Pennetta F./Schiavone F. | 2:1 (6:1, 5:7, 7:6) | details | 08.01.2010 |
| Quarter-finals | Pennetta F./Schiavone F. | Borwell S./Atawo R. | 2:0 (7:6, 6:4) | details | 06.01.2010 |
| 1/8-finals | Pennetta F./Schiavone F. | Gallovits E./Peer S. | 2:1 (7:5, 2:6, 7:6) | details | 05.01.2010 |
World: Olympic Games - Doubles - Main |
| Quarter-finals | Bondarenko A./Volodko K. | Pennetta F./Schiavone F. | 2:1 (6:1, 3:6, 7:5) | details | 15.08.2008 |
| 1/8-finals | Pennetta F./Schiavone F. | Chan L./Chuang C.-J. | 2:1 (7:6, 1:6, 7:6) | details | 13.08.2008 |
| 1/16-finals | DellAcqua C./Molik A. | Pennetta F./Schiavone F. | 0:2 (4:6, 4:6) | details | 12.08.2008 |
USA: Miami - Doubles - Main |
| 1/16-finals | Azarenka V./Peer S. | Pennetta F./Schiavone F. | 2:1 (7:6, 6:7, 7:6) | details | 29.03.2008 |
USA: Indian Wells - Doubles - Main |
| 1/8-finals | Pennetta F./Schiavone F. | Yan Z./Zheng J. | 1:2 (6:4, 1:6, 6:7) | details | 17.03.2008 |
| 1/16-finals | Hsieh S-W./King V. | Pennetta F./Schiavone F. | 0:2 (1:6, 2:6) | details | 12.03.2008 |
Australia: Gold Coast - Singles - Main |
| Quarter-finals | Black C./Huber L. | Pennetta F./Schiavone F. | 2:1 (6:7, 6:4, 7:6) | details | 03.01.2008 |
| 1/8-finals | Kustova D./Poutchek T. | Pennetta F./Schiavone F. | 0:2 (2:6, 1:6) | details | 02.01.2008 |
Australia: Sydney - Doubles - Main |
| Quarter-finals | Pennetta F./Schiavone F. | Dementieva E./Sugiyama A. | 1:2 (3:6, 6:2, 6:7) | details | 12.01.2005 |
| 1/8-finals | Pennetta F./Schiavone F. | Daniilidou E./Golovin T. | 0:0 WO. | details | 11.01.2005 |